Specifications
- Purity
- ≥95% (T)
- Appearance
- White crystalline
- Identity
- 1H-NMR
Properties
- Solvents
- DMSO
Downloads
- Safety Data Sheet
- CDX I0027 MSDS.pdf
Category: Building Blocks, Intermediates, Reagents
Hypervalent iodine reagents. Convenient substitute of o-Iodosobenzoic acid (IBA) as an oxidant. Can be used for installations of a/b-unsaturation to carbonyl compounds, oxidations and cyclizations by single-electron transfer processes. Promotes faster reactions than IBA with better solubility in common organic solvents. An attractive feature is the ability to directly measure reactivity by 19F NMR spectroscopy without the use of deuterated solvents.
Synonyms | FIBA Tetrafluoro-IBA, 4,5,6,7-Tetrafluoro-1-hydroxy-1,2-benziodoxole-3(1H)-one |
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Purity | ≥95% (T) |
Appearance | White crystalline |
CAS-Number | 954373-94-5 |
Molecular Formula | C7HF4IO3 |
Molecular Weight | 335.98 |
Identity | 1H-NMR |
Solvents | DMSO |
Smiles | FC1=C2C(C(OI2O)=O)=C(F)C(F)=C1F |
InChi Key | ZJHDTMPJHPTADJ-UHFFFAOYSA-N |
Shipping | AMBIENT |
Short Term Storage | +4°C |
Long Term Storage | -20°C |
Handling Advice | Protect from light and moisture. |
Use / Stability | Stable for at least 2 years after receipt when stored at -20°C. |
References | (1) R. Richardson, et al.: Angew. Chem. Int. Ed. 46, 6529 (2007) |
InChi | InChI=1S/C7HF4IO3/c8-2-1-6(12(14)15-7(1)13)5(11)4(10)3(2)9/h14H |
Quantity | 1 g, 5 g, Bulk |