Available from stock

2-Iodoso-3,4,5,6-tetrafluorobenzoic acid

SKU: I0027

Category: Building Blocks, Intermediates, Reagents

Synonyms: FIBA Tetrafluoro-IBA , 4,5,6,7-Tetrafluoro-1-hydroxy-1,2-benziodoxole-3(1H)-one; 954373-94-5
CAS-Number: C₇HF₄IO₃
Molecular Formula: 335.98
Molecular Weight

For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.

Product Data
Handling
Safety Information
Details

Specifications

Purity: ≥95% (T)
Appearance: White crystalline
Identity: 1H-NMR

Properties

Solvents: DMSO

Documentation

Safety Data Sheet (SDS): CDX I0027 MSDS.pdf

Shipping: AMBIENT
Short Term Storage: +4°C
Long Term Storage: -20°C
Handling Advice: Protect from light and moisture.
Use / Stability: Stable for at least 2 years after receipt when stored at -20°C.

Description: Hypervalent iodine reagents. Convenient substitute of o-Iodosobenzoic acid (IBA) as an oxidant. Can be used for installations of a/b-unsaturation to carbonyl compounds, oxidations and cyclizations by single-electron transfer processes. Promotes faster reactions than IBA with better solubility in common organic solvents. An attractive feature is the ability to directly measure reactivity by 19F NMR spectroscopy without the use of deuterated solvents.
Smiles: FC1=C2C(C(OI2O)=O)=C(F)C(F)=C1F
InChi Key: ZJHDTMPJHPTADJ-UHFFFAOYSA-N
References: (1) R. Richardson, et al.: Angew. Chem. Int. Ed. 46, 6529 (2007)
InChi: InChI=1S/C7HF4IO3/c8-2-1-6(12(14)15-7(1)13)5(11)4(10)3(2)9/h14H

Hypervalent iodine reagents. Convenient substitute of o-Iodosobenzoic acid (IBA) as an oxidant. Can be used for installations of a/b-unsaturation to carbonyl compounds, oxidations and cyclizations by single-electron transfer processes. Promotes faster reactions than IBA with better solubility in common organic solvents. An attractive feature is the ability to directly measure reactivity by 19F NMR spectroscopy without the use of deuterated solvents.

SKU: I0027 Category: Building Blocks, Intermediates, Reagents

Additional information

Additional information

Synonyms	FIBA Tetrafluoro-IBA, 4,5,6,7-Tetrafluoro-1-hydroxy-1,2-benziodoxole-3(1H)-one
Purity	≥95% (T)
Appearance	White crystalline
CAS-Number	954373-94-5
Molecular Formula	C7HF4IO3
Molecular Weight	335.98
Identity	1H-NMR
Solvents	DMSO
Smiles	FC1=C2C(C(OI2O)=O)=C(F)C(F)=C1F
InChi Key	ZJHDTMPJHPTADJ-UHFFFAOYSA-N
Shipping	AMBIENT
Short Term Storage	+4°C
Long Term Storage	-20°C
Handling Advice	Protect from light and moisture.
Use / Stability	Stable for at least 2 years after receipt when stored at -20°C.
References	(1) R. Richardson, et al.: Angew. Chem. Int. Ed. 46, 6529 (2007)
InChi	InChI=1S/C7HF4IO3/c8-2-1-6(12(14)15-7(1)13)5(11)4(10)3(2)9/h14H
Quantity	1 g, 5 g, Bulk