Available from stock

2-Nitrophenyl dodecyl ether

SKU: N0277

Categories:

Synonyms: ETH 217 , Dodecyl 2-nitrophenyl ether , 1-Dodecyloxy-2-nitrobenzene , NPDDE , DDNPE; 83027-71-8
CAS-Number: C₁₈H₂₉NO₃
Molecular Formula: 307.43
Molecular Weight

For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.

Product Data
Handling
Safety Information
Details

Specifications

Purity: ≥99% (GC)
Appearance: Yellow to green liquid
Identity: 1H-NMR

Properties

Solvents: chloroform
Boiling Point: 218 °C/1.5 mmHg (lit.)
Refractive Index: n20/D 1.510-1.512
Density: 0.999 g/ml at 20 °C (lit.)

Shipping: AMBIENT
Short Term Storage: +4°C
Long Term Storage: -20°C
Handling Advice: Protect from light and moisture.
Use / Stability: Stable for at least 2 years after receipt when stored at -20°C.

Transportation: Not dangerous goods

Description: 2-Nitrophenyl dodecyl ether (ETh 217) is a plasticizer for solvent polymeric membranes in ion-selective electrodes that has been used for over 30 years. It exhibits desirable lipophilicity characteristics without apparent deteriorating influence on ion selectivity. It is used as a highly viscous plasticizer (solid at room temperature) and PVC as a membrane matrix for nitrate ISFETs. As a nitro-aromatic solvent it was also used to enhance extraction of nonpolar drugs during a study to demonstrate different approaches of basic drugs to maximize extraction recovery using electro membrane extraction method.
Smiles: CCCCCCCCCCCCOC1=C([N+]([O-])=O)C=CC=C1
InChi Key: DXCTUMLYTQODSP-UHFFFAOYSA-N
References: (1) K. Fluri, et al., Helv. Chim. Acta 75, 1012 (1992) , (2) R. Yuan, et al., Anal. Chem. 65, 2572 (1993) , (3) R. Eugster, et al., Anal. Chim. Acta 289, 1 (1994) , (4) T. Sasaki, et al., J. Incl. Phen. Mol. Rec. Chem. 17, 377 (1994) , (5) F.J. Keplinger, et al., Anal. Chem. 70, 4271 (1998) , (6) S.-I. Wakida, et al., Sens. Actuat. B Chem. 66, 153 (2000) , (7) T. Masadome, et al., Microchim. Acta 144, 217 (2004) , (8) S.-I. Wakida, et al., Sens. Mat. 19, 235 (2007) , (9) K. Wygladacz, et al., Anal. Chim. Acta 614, 77 (2008) , (10) T. Masadome, et al., Anal. Sci. 26, 417 (2010) , (11) E. Grygolowicz-Pawlak & E. Bakker, Anal. Chem. 82, 4537 (2010) , (12) B. Neel, et al., Electroanal. 26, 473 (2014) , (13) S. Osaki, et al., Sensors 19, 2713 (2019)
InChi: InChI=1S/C18H29NO3/c1-2-3-4-5-6-7-8-9-10-13-16-22-18-15-12-11-14-17(18)19(20)21/h11-12,14-15H,2-10,13,16H2,1H3

2-Nitrophenyl dodecyl ether (ETh 217) is a plasticizer for solvent polymeric membranes in ion-selective electrodes that has been used for over 30 years. It exhibits desirable lipophilicity characteristics without apparent deteriorating influence on ion selectivity. It is used as a highly viscous plasticizer (solid at room temperature) and PVC as a membrane matrix for nitrate ISFETs. As a nitro-aromatic solvent it was also used to enhance extraction of nonpolar drugs during a study to demonstrate different approaches of basic drugs to maximize extraction recovery using electro membrane extraction method.

SKU: N0277

Additional information

Additional information

Synonyms	ETH 217, Dodecyl 2-nitrophenyl ether, 1-Dodecyloxy-2-nitrobenzene, NPDDE, DDNPE
Purity	≥99% (GC)
Appearance	Yellow to green liquid
CAS-Number	83027-71-8
Molecular Formula	C18H29NO3
Molecular Weight	307.43
Identity	1H-NMR
Solvents	chloroform
Boiling Point	218 °C/1.5 mmHg (lit.)
Refractive Index	n20/D 1.510-1.512
Density	0.999 g/ml at 20 °C (lit.)
Smiles	CCCCCCCCCCCCOC1=C([N+]([O-])=O)C=CC=C1
InChi Key	DXCTUMLYTQODSP-UHFFFAOYSA-N
Shipping	AMBIENT
Short Term Storage	+4°C
Long Term Storage	-20°C
Handling Advice	Protect from light and moisture.
Use / Stability	Stable for at least 2 years after receipt when stored at -20°C.
Transportation	Not dangerous goods
References	(1) K. Fluri, et al., Helv. Chim. Acta 75, 1012 (1992), (2) R. Yuan, et al., Anal. Chem. 65, 2572 (1993), (3) R. Eugster, et al., Anal. Chim. Acta 289, 1 (1994), (4) T. Sasaki, et al., J. Incl. Phen. Mol. Rec. Chem. 17, 377 (1994), (5) F.J. Keplinger, et al., Anal. Chem. 70, 4271 (1998), (6) S.-I. Wakida, et al., Sens. Actuat. B Chem. 66, 153 (2000), (7) T. Masadome, et al., Microchim. Acta 144, 217 (2004), (8) S.-I. Wakida, et al., Sens. Mat. 19, 235 (2007), (9) K. Wygladacz, et al., Anal. Chim. Acta 614, 77 (2008), (10) T. Masadome, et al., Anal. Sci. 26, 417 (2010), (11) E. Grygolowicz-Pawlak & E. Bakker, Anal. Chem. 82, 4537 (2010), (12) B. Neel, et al., Electroanal. 26, 473 (2014), (13) S. Osaki, et al., Sensors 19, 2713 (2019)
InChi	InChI=1S/C18H29NO3/c1-2-3-4-5-6-7-8-9-10-13-16-22-18-15-12-11-14-17(18)19(20)21/h11-12,14-15H,2-10,13,16H2,1H3
Quantity	5 ml, Bulk