Specifications
- Purity
- ≥97%
- Appearance
- Light brown powder
- Identity
- 1H-NMR
Properties
- Solvents
- water (partly), ethanol, chloroform, methanol, and acetone
- Melting Point
- 132-134 °C (lit.)
Available from stock
8-Hydroxyjulolidine
- SKU
- H0025
Category: Building Blocks, Intermediates, Reagents
- Synonyms
- 2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizin-8-ol
- 41175-50-2
- CAS-Number
- C12H15NO
- Molecular Formula
- 189.25
- Molecular Weight
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
- Shipping
- AMBIENT
- Short Term Storage
- RT
- Long Term Storage
- RT
- Handling Advice
- Protect from light and moisture.
- Use / Stability
- Stable for at least 2 years after receipt when stored at RT.
- Hazard statements
- H315-H319-H335
- Precautionary statements
- P261-P305 + P351 + P338
- GHS Symbol
- GHS07
- Signal word
- Warning
- Transportation
- Not dangerous goods
- Description
- An intermediate and starting material for various coumarin syntheses. Used to prepare aminocoumarins via microwave-accelerated Pechmann reaction or as starting material for coumarin C-ribosides.
- Smiles
- OC1=C2C3=C(CCCN3CCC2)C=C1
- InChi Key
- FOFUWJNBAQJABO-UHFFFAOYSA-N
- References
- (1) M.-T. Le Bris, J. Heterocyc. Chem. 26, 429 (1989) , (2) J.M. Kauffmann, et al., Org. Prep. Proc. Int. 33, 603 (2001) , (3) J. Jose & K. Burgess, Tetrahed. 62, 11021 (2006) , (4) J. Uddin & L.J. Marnett, Org. Lett. 10, 4799 (2008) , (5) L.F. Mottram, et al., J. Org. Chem. 8, 2156 (2012) , (6) G.K. Hodgson, et al., Chem. Sci. (Epub ahead) (2016)
- InChi
- InChI=1S/C12H15NO/c14-11-6-5-9-3-1-7-13-8-2-4-10(11)12(9)13/h5-6,14H,1-4,7-8H2
An intermediate and starting material for various coumarin syntheses. Used to prepare aminocoumarins via microwave-accelerated Pechmann reaction or as starting material for coumarin C-ribosides.
Additional information
| Synonyms | 2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizin-8-ol |
|---|---|
| Purity | ≥97% |
| Appearance | Light brown powder |
| CAS-Number | 41175-50-2 |
| Molecular Formula | C12H15NO |
| Molecular Weight | 189.25 |
| Identity | 1H-NMR |
| Solvents | water (partly), ethanol, chloroform, methanol, and acetone |
| Melting Point | 132-134 °C (lit.) |
| Smiles | OC1=C2C3=C(CCCN3CCC2)C=C1 |
| InChi Key | FOFUWJNBAQJABO-UHFFFAOYSA-N |
| Shipping | AMBIENT |
| Short Term Storage | RT |
| Long Term Storage | RT |
| Handling Advice | Protect from light and moisture. |
| Use / Stability | Stable for at least 2 years after receipt when stored at RT. |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P305 + P351 + P338 |
| GHS Symbol | GHS07 |
| Signal word | Warning |
| Transportation | Not dangerous goods |
| References | (1) M.-T. Le Bris, J. Heterocyc. Chem. 26, 429 (1989), (2) J.M. Kauffmann, et al., Org. Prep. Proc. Int. 33, 603 (2001), (3) J. Jose & K. Burgess, Tetrahed. 62, 11021 (2006), (4) J. Uddin & L.J. Marnett, Org. Lett. 10, 4799 (2008), (5) L.F. Mottram, et al., J. Org. Chem. 8, 2156 (2012), (6) G.K. Hodgson, et al., Chem. Sci. (Epub ahead) (2016) |
| InChi | InChI=1S/C12H15NO/c14-11-6-5-9-3-1-7-13-8-2-4-10(11)12(9)13/h5-6,14H,1-4,7-8H2 |
| Quantity | 1 g, 5 g, 25 g, Bulk |
