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    Bis(4-tert-butylphenyl)iodonium hexafluorophosphate

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      Bis(4-tert-butylphenyl)iodonium hexafluorophosphate

      SKU
      T0106

      Category: Building Blocks, Intermediates, Reagents

      Synonyms
      WPI-170 , DtBPI-PF6 , BTIH
      61358-25-6
      CAS-Number
      C20H26F6IP
      Molecular Formula
      538.29
      Molecular Weight

      For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.

      • Product Data
      • Handling
      • Safety Information
      • Details

      Specifications

      Purity
      ≥98% (TLC)
      Appearance
      White crystalline powder
      Identity
      1H-NMR

      Properties

      Solvents
      chloroform, ethanol, ethyl acetate, acetone, methanol, water (insoluble)
      Shipping
      AMBIENT
      Short Term Storage
      +4°C
      Long Term Storage
      -20°C
      Handling Advice
      Protect from light and moisture.
      Use / Stability
      Stable for at least 2 years after receipt when stored at -20°C.
      Hazard statements
      H314
      Precautionary statements
      P280, P305 + P351 + P338, P310
      GHS Symbol
      GHS05
      Signal word
      Danger
      RIDADR
      UN1759
      Transportation
      Excepted Quantities
      Description
      Bis(4-tert-Butylphenyl) iodoniumhexafluorophosphate is a photo-cationic polymerization initiator that is used for chemical synthesis in materials science and micro/nano electronics. Photopolymerization initiators are used in many fields to generate photocurable composites. These composites are polymerized by irradiation with UV light and electron beam which leads to altered physical properties of the composites such as solubility, viscosity and adhesiveness.
      Smiles
      CC(C)(C)C1=CC=C([I+]C2=CC=C(C(C)(C)C)C=C2)C=C1.F[P-](F)(F)([F+2])(F)F
      InChi Key
      CJLLNCQWBHTSCB-UHFFFAOYSA-N
      References
      (1) M. Ueki & M. Yamaguchi, Rapid Commun. Mass Spectrom. 20, 1615 (2006) , (2) J.J. McDowell, et al., ACS Appl. Mater. Interfaces 6, 83 (2014) , (3) T. Helbich, etal., Nanoscale 9, 7739 (2017)
      InChi
      InChI=1S/C20H26I.F6P/c1-19(2,3)15-7-11-17(12-8-15)21-18-13-9-16(10-14-18)20(4,5)6,1-7(2,3,4,5)6/h7-14H,1-6H3,/q+1,-1

      Bis(4-tert-Butylphenyl) iodoniumhexafluorophosphate is a photo-cationic polymerization initiator that is used for chemical synthesis in materials science and micro/nano electronics. Photopolymerization initiators are used in many fields to generate photocurable composites. These composites are polymerized by irradiation with UV light and electron beam which leads to altered physical properties of the composites such as solubility, viscosity and adhesiveness.

      SKU: T0106 Category: Building Blocks, Intermediates, Reagents
      • Additional information

      Additional information

      Synonyms

      WPI-170, DtBPI-PF6, BTIH

      Purity

      ≥98% (TLC)

      Appearance

      White crystalline powder

      CAS-Number

      61358-25-6

      Molecular Formula

      C20H26F6IP

      Molecular Weight

      538.29

      Identity

      1H-NMR

      Solvents

      chloroform, ethanol, ethyl acetate, acetone, methanol, water (insoluble)

      Smiles

      CC(C)(C)C1=CC=C([I+]C2=CC=C(C(C)(C)C)C=C2)C=C1.F[P-](F)(F)([F+2])(F)F

      InChi Key

      CJLLNCQWBHTSCB-UHFFFAOYSA-N

      Shipping

      AMBIENT

      Short Term Storage

      +4°C

      Long Term Storage

      -20°C

      Handling Advice

      Protect from light and moisture.

      Use / Stability

      Stable for at least 2 years after receipt when stored at -20°C.

      Hazard statements

      H314

      Precautionary statements

      P280, P305 + P351 + P338, P310

      GHS Symbol

      GHS05

      Signal word

      Danger

      RIDADR

      UN1759

      Transportation

      Excepted Quantities

      References

      (1) M. Ueki & M. Yamaguchi, Rapid Commun. Mass Spectrom. 20, 1615 (2006), (2) J.J. McDowell, et al., ACS Appl. Mater. Interfaces 6, 83 (2014), (3) T. Helbich, etal., Nanoscale 9, 7739 (2017)

      InChi

      InChI=1S/C20H26I.F6P/c1-19(2,3)15-7-11-17(12-8-15)21-18-13-9-16(10-14-18)20(4,5)6,1-7(2,3,4,5)6/h7-14H,1-6H3,/q+1,-1

      Quantity

      1 g, 10 g, 100 g, Bulk

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