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    (S)-a-Methoxy-2-naphthylacetic acid

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      (S)-a-Methoxy-2-naphthylacetic acid

      SKU
      M0213

      Category: Building Blocks, Intermediates, Reagents

      Synonyms
      (S)-2-NMA , (S)-α-Methoxy-2-naphthaleneacetic acid
      157134-51-5
      CAS-Number
      C13H12O3
      Molecular Formula
      216.23
      Molecular Weight

      • Product Data
      • Handling
      • Safety Information
      • Details

      Specifications

      Purity
      ≥97% (HPLC)
      Identity
      1H-NMR
      Appearance
      White powder

      Properties

      Optical Activity
      [α]/D +177±5°, c = 0.1 in methanol
      Melting Point
      101-104 °C
      Solvents
      methanol

      Downloads

      Safety Data Sheet
      CDX M0213 MSDS.pdf
      Handling Advice
      Protect from light and moisture.
      Use / Stability
      Stable for at least 2 years after receipt when stored at -20°C.
      Long Term Storage
      -20°C
      Short Term Storage
      +4°C
      Shipping
      AMBIENT
      Transportation
      Packing Group III
      RIDADR
      UN2811 6.1
      Signal word
      Danger
      GHS Symbol
      GHS06
      Precautionary statements
      P301 + P310
      Hazard statements
      H301
      Description
      Excellent chiral anisotropic NMR reagent. Used for the determination of the absolute configuration of secondary alcohols.
      InChi
      InChI=1S/C13H12O3/c1-16-12(13(14)15)11-7-6-9-4-2-3-5-10(9)8-11/h2-8,12H,1H3,(H,14,15)
      References
      (1) T. Kusumi, et al.: Tetrahed. Lett. 35, 4397 (1994) , (2) N. Gautier, et al.: Tetrahed. Assym. 8, 501 (1997) , (3) L. Fauconnot, et al.: Tetrahed. Lett. 38, 7875 (1997) , (4) P. Duret, et al.: J. Org. Chem. 63, 4717 (1998) , (5) M. Kimura, et al.: Tetrahed. Assym. 13, 1059 (2002)
      InChi Key
      OQVFHDWREDKUCW-UHFFFAOYSA-N
      Smiles
      CO[C@H](C(O)=O)C1=CC2=CC=CC=C2C=C1

      Excellent chiral anisotropic NMR reagent. Used for the determination of the absolute configuration of secondary alcohols.

      SKU: M0213 Category: Building Blocks, Intermediates, Reagents
      • Additional information

      Additional information

      Synonyms

      (S)-2-NMA, (S)-α-Methoxy-2-naphthaleneacetic acid

      Purity

      ≥97% (HPLC)

      Appearance

      White powder

      CAS-Number

      157134-51-5

      Molecular Formula

      C13H12O3

      Molecular Weight

      216.23

      Identity

      1H-NMR

      Solvents

      methanol

      Melting Point

      101-104 °C

      Optical Activity

      [α]/D +177±5°, c = 0.1 in methanol

      Smiles

      CO[C@H](C(O)=O)C1=CC2=CC=CC=C2C=C1

      InChi Key

      OQVFHDWREDKUCW-UHFFFAOYSA-N

      Shipping

      AMBIENT

      Short Term Storage

      +4°C

      Long Term Storage

      -20°C

      Handling Advice

      Protect from light and moisture.

      Use / Stability

      Stable for at least 2 years after receipt when stored at -20°C.

      Hazard statements

      H301

      Precautionary statements

      P301 + P310

      GHS Symbol

      GHS06

      Signal word

      Danger

      RIDADR

      UN2811 6.1

      Transportation

      Packing Group III

      References

      (1) T. Kusumi, et al.: Tetrahed. Lett. 35, 4397 (1994), (2) N. Gautier, et al.: Tetrahed. Assym. 8, 501 (1997), (3) L. Fauconnot, et al.: Tetrahed. Lett. 38, 7875 (1997), (4) P. Duret, et al.: J. Org. Chem. 63, 4717 (1998), (5) M. Kimura, et al.: Tetrahed. Assym. 13, 1059 (2002)

      InChi

      InChI=1S/C13H12O3/c1-16-12(13(14)15)11-7-6-9-4-2-3-5-10(9)8-11/h2-8,12H,1H3,(H,14,15)

      Quantity

      100 mg, 500 mg, Bulk

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