Sorbic chloride

Available from stock

Sorbic chloride

SKU
S0036

Category:

Synonyms
Sorbyl chloride , (2E,4E)-2,4-Hexadienoyl chloride , (E,E)-2,4-Hexadienoyl chloride , trans,trans-2,4-Hexadienoyl chloride , Sorbic acid chloride
2614-88-2
CAS-Number
C6H7ClO
Molecular Formula
130.57
Molecular Weight

For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.

Specifications

Purity
≥80% (GC)
Appearance
Colourless to yellow liquid
Identity
1H-NMR

Properties

Solvents
water, CH2Cl2
Boiling Point
45.5 °C at 12 Torr
Density
1.0666 g/cm3 at 18.75 °C

Documentation

Safety Data Sheet (SDS)
CDX S0036 MSDS.pdf
Shipping
AMBIENT
Short Term Storage
+4°C
Long Term Storage
-20°C
Handling Advice
Protect from light and moisture.
Use / Stability
Stable for at least 2 years after receipt when stored at -20°C.
Hazard statements
H314
Precautionary statements
P264, P280, P301 + P330 + P331, P303 + P361 + P353, P304 + P340, P305 + P351 + P338, P310
GHS Symbol
GHS05
Signal word
Danger
RIDADR
UN3265 8
Transportation
Packing Group II
Description
Reactant for: (1) preparation of unsaturated hydroxymethylene diphosphonic acid derivatives by reaction of trimethylsilyl phosphites, (2) asymmetrical synthesis of the isoindolinone subunit of the macrocyclic poylketide natural product muironolide via stereoselective intramolecular Diels-Alder cycloaddition, (3) preparation of emollient, humectant, and fluorescent ?,?-unsaturated thiol esters for long-acting skin applications, (4) stereoselective synthesis of enediol carbonates for use in the asymmetrical synthesis of ?-acyloxyketones, (5) acylation of pyrazoles.
Smiles
C/C=C/C=C/C(Cl)=O
InChi Key
GRTWTVFDPBKQNU-MQQKCMAXSA-N
References
(1) K. Itoh, et al.: Org. Lett. 7, 979 (2005) , (2) B.M Trost, et al.: JACS 130, 11852 (2008) , (3) C. Robinson, et al.: Bioorg. Chem. 36, 265 (2008) , (4) B. Flores & T.F. Molinski: Org. Lett. 13, 3932 (2011) , (5) A.A. Prishchenko, et al.: Russ. J. Gen. Chem. 81, 1730 (2011)
InChi
InChI=1S/C6H7ClO/c1-2-3-4-5-6(7)8/h2-5H,1H3/b3-2+,5-4+

Reactant for: (1) preparation of unsaturated hydroxymethylene diphosphonic acid derivatives by reaction of trimethylsilyl phosphites, (2) asymmetrical synthesis of the isoindolinone subunit of the macrocyclic poylketide natural product muironolide via stereoselective intramolecular Diels-Alder cycloaddition, (3) preparation of emollient, humectant, and fluorescent ?,?-unsaturated thiol esters for long-acting skin applications, (4) stereoselective synthesis of enediol carbonates for use in the asymmetrical synthesis of ?-acyloxyketones, (5) acylation of pyrazoles.

SKU: S0036 Category:

Additional information

Synonyms

Sorbyl chloride, (2E,4E)-2,4-Hexadienoyl chloride, (E,E)-2,4-Hexadienoyl chloride, trans,trans-2,4-Hexadienoyl chloride, Sorbic acid chloride
Purity

≥80% (GC)
Appearance

Colourless to yellow liquid
CAS-Number

2614-88-2
Molecular Formula

C6H7ClO
Molecular Weight

130.57
Identity

1H-NMR
Solvents

water, CH2Cl2
Boiling Point

45.5 °C at 12 Torr
Density

1.0666 g/cm3 at 18.75 °C
Smiles

C/C=C/C=C/C(Cl)=O
InChi Key

GRTWTVFDPBKQNU-MQQKCMAXSA-N
Shipping

AMBIENT
Short Term Storage

+4°C
Long Term Storage

-20°C
Handling Advice

Protect from light and moisture.
Use / Stability

Stable for at least 2 years after receipt when stored at -20°C.
Hazard statements

H314
Precautionary statements

P264, P280, P301 + P330 + P331, P303 + P361 + P353, P304 + P340, P305 + P351 + P338, P310
GHS Symbol

GHS05
Signal word

Danger
RIDADR

UN3265 8
Transportation

Packing Group II
References

(1) K. Itoh, et al.: Org. Lett. 7, 979 (2005), (2) B.M Trost, et al.: JACS 130, 11852 (2008), (3) C. Robinson, et al.: Bioorg. Chem. 36, 265 (2008), (4) B. Flores & T.F. Molinski: Org. Lett. 13, 3932 (2011), (5) A.A. Prishchenko, et al.: Russ. J. Gen. Chem. 81, 1730 (2011)
InChi

InChI=1S/C6H7ClO/c1-2-3-4-5-6(7)8/h2-5H,1H3/b3-2+,5-4+
Quantity

1 g, 5 g, Bulk

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