Specifications
- Purity
- ≥80% (GC)
- Identity
- 1H-NMR
- Appearance
- Colourless to yellow liquid
Properties
- Density
- 1.0666 g/cm3 at 18.75 °C
- Boiling Point
- 45.5 °C at 12 Torr
- Solvents
- water, CH2Cl2
Downloads
- Safety Data Sheet
- CDX S0036 MSDS.pdf
Available from stock
Sorbic chloride
- SKU
- S0036
Category: Building Blocks, Intermediates, Reagents
- Synonyms
- Sorbyl chloride , (2E,4E)-2,4-Hexadienoyl chloride , (E,E)-2,4-Hexadienoyl chloride , trans,trans-2,4-Hexadienoyl chloride , Sorbic acid chloride
- 2614-88-2
- CAS-Number
- C6H7ClO
- Molecular Formula
- 130.57
- Molecular Weight
- Handling Advice
- Protect from light and moisture.
- Use / Stability
- Stable for at least 2 years after receipt when stored at -20°C.
- Long Term Storage
- -20°C
- Short Term Storage
- +4°C
- Shipping
- AMBIENT
- Transportation
- Packing Group II
- RIDADR
- UN3265 8
- Signal word
- Danger
- GHS Symbol
- GHS05
- Precautionary statements
- P264, P280, P301 + P330 + P331, P303 + P361 + P353, P304 + P340, P305 + P351 + P338, P310
- Hazard statements
- H314
- Description
- Reactant for: (1) preparation of unsaturated hydroxymethylene diphosphonic acid derivatives by reaction of trimethylsilyl phosphites, (2) asymmetrical synthesis of the isoindolinone subunit of the macrocyclic poylketide natural product muironolide via stereoselective intramolecular Diels-Alder cycloaddition, (3) preparation of emollient, humectant, and fluorescent ?,?-unsaturated thiol esters for long-acting skin applications, (4) stereoselective synthesis of enediol carbonates for use in the asymmetrical synthesis of ?-acyloxyketones, (5) acylation of pyrazoles.
- InChi
- InChI=1S/C6H7ClO/c1-2-3-4-5-6(7)8/h2-5H,1H3/b3-2+,5-4+
- References
- (1) K. Itoh, et al.: Org. Lett. 7, 979 (2005) , (2) B.M Trost, et al.: JACS 130, 11852 (2008) , (3) C. Robinson, et al.: Bioorg. Chem. 36, 265 (2008) , (4) B. Flores & T.F. Molinski: Org. Lett. 13, 3932 (2011) , (5) A.A. Prishchenko, et al.: Russ. J. Gen. Chem. 81, 1730 (2011)
- InChi Key
- GRTWTVFDPBKQNU-MQQKCMAXSA-N
- Smiles
- C/C=C/C=C/C(Cl)=O
Reactant for: (1) preparation of unsaturated hydroxymethylene diphosphonic acid derivatives by reaction of trimethylsilyl phosphites, (2) asymmetrical synthesis of the isoindolinone subunit of the macrocyclic poylketide natural product muironolide via stereoselective intramolecular Diels-Alder cycloaddition, (3) preparation of emollient, humectant, and fluorescent ?,?-unsaturated thiol esters for long-acting skin applications, (4) stereoselective synthesis of enediol carbonates for use in the asymmetrical synthesis of ?-acyloxyketones, (5) acylation of pyrazoles.
Additional information
| Synonyms | Sorbyl chloride, (2E,4E)-2,4-Hexadienoyl chloride, (E,E)-2,4-Hexadienoyl chloride, trans,trans-2,4-Hexadienoyl chloride, Sorbic acid chloride |
|---|---|
| Purity | ≥80% (GC) |
| Appearance | Colourless to yellow liquid |
| CAS-Number | 2614-88-2 |
| Molecular Formula | C6H7ClO |
| Molecular Weight | 130.57 |
| Identity | 1H-NMR |
| Solvents | water, CH2Cl2 |
| Boiling Point | 45.5 °C at 12 Torr |
| Density | 1.0666 g/cm3 at 18.75 °C |
| Smiles | C/C=C/C=C/C(Cl)=O |
| InChi Key | GRTWTVFDPBKQNU-MQQKCMAXSA-N |
| Shipping | AMBIENT |
| Short Term Storage | +4°C |
| Long Term Storage | -20°C |
| Handling Advice | Protect from light and moisture. |
| Use / Stability | Stable for at least 2 years after receipt when stored at -20°C. |
| Hazard statements | H314 |
| Precautionary statements | P264, P280, P301 + P330 + P331, P303 + P361 + P353, P304 + P340, P305 + P351 + P338, P310 |
| GHS Symbol | GHS05 |
| Signal word | Danger |
| RIDADR | UN3265 8 |
| Transportation | Packing Group II |
| References | (1) K. Itoh, et al.: Org. Lett. 7, 979 (2005), (2) B.M Trost, et al.: JACS 130, 11852 (2008), (3) C. Robinson, et al.: Bioorg. Chem. 36, 265 (2008), (4) B. Flores & T.F. Molinski: Org. Lett. 13, 3932 (2011), (5) A.A. Prishchenko, et al.: Russ. J. Gen. Chem. 81, 1730 (2011) |
| InChi | InChI=1S/C6H7ClO/c1-2-3-4-5-6(7)8/h2-5H,1H3/b3-2+,5-4+ |
| Quantity | 1 g, 5 g, Bulk |
