(1S)-(+)-3-Bromocamphor-10-sulfonic acid hydrate

Category: Building Blocks, Intermediates, Reagents

Handling Advice: Protect from light and moisture.
Use / Stability: Stable for at least 2 years after receipt when stored at -20°C.
Long Term Storage: -20°C
Short Term Storage: +4°C
Shipping: AMBIENT

Description: Chiral reagent used for the resolution of bases. Building block for synthesis.
InChi: InChI=1S/C10H15BrO4S.H2O/c1-9(2)6-3-4-10(9,5-16(13,14)15)8(12)7(6)11
References: (1) P.H. Boyle , Quart. Rev. 25, 323 (1971) , (2) S.H. Wilen , Top. Stereochem. 6, 107 (1971)
InChi Key: RQZLIPHNDCFLPR-OFVIFIGMSA-N
Smiles: O=C1[C@@H](Br)[C@H]2CC[C@]1(CS(=O)(O)=O)C2(C)C.O

Chiral reagent used for the resolution of bases. Building block for synthesis.

Additional information

Purity	≥98% (TLC )
Appearance	Beige crystalline
CAS-Number	206860-46-0
Molecular Formula	C10H15BrO4S . xH2O
Molecular Weight	311.19 (anhydrous basis)
Identity	1H-NMR
Solvents	methanol or water
Melting Point	117-121 °C (lit.)
Optical Activity	[α]20/D +94°, c = 1 in H2O
Smiles	O=C1[C@@H](Br)[C@H]2CC[C@]1(CS(=O)(O)=O)C2(C)C.O
InChi Key	RQZLIPHNDCFLPR-OFVIFIGMSA-N
Shipping	AMBIENT
Short Term Storage	+4°C
Long Term Storage	-20°C
Handling Advice	Protect from light and moisture.
Use / Stability	Stable for at least 2 years after receipt when stored at -20°C.
Hazard statements	H314
Precautionary statements	P280-P305 + P351 + P338-P310
GHS Symbol	GHS05
Signal word	Danger
RIDADR	UN3261 8
Transportation	Packing Group II
References	(1) P.H. Boyle, Quart. Rev. 25, 323 (1971), (2) S.H. Wilen, Top. Stereochem. 6, 107 (1971)
InChi	InChI=1S/C10H15BrO4S.H2O/c1-9(2)6-3-4-10(9,5-16(13,14)15)8(12)7(6)11
Quantity	250 mg, 1 g, Bulk