Specifications
- Purity
- ≥98% (NMR)
- Appearance
- Light yellow crystalline
- Identity
- 1H-NMR
Properties
- Solvents
- acetone, chloroform, DMSO
- Melting Point
- 180-181°C (lit.)
Category: Building Blocks, Intermediates, Reagents
Reagent for synthesis. Used for α?phenylation of cyclic ketones, N?, O?, P?, and S?phenylation reactions. Phenylating agent for palladium?catalyzed cross?couplings, click chemistry and photochemistry.
Synonyms | DPIT, Diphenyliodonium trifluoromethanesulfonate |
---|---|
Purity | ≥98% (NMR) |
Appearance | Light yellow crystalline |
CAS-Number | 66003-76-7 |
Molecular Formula | C13H10F3IO3S |
Molecular Weight | 430.18 |
Identity | 1H-NMR |
Solvents | acetone, chloroform, DMSO |
Melting Point | 180-181°C (lit.) |
Smiles | [O-]S(=O)(C(F)(F)F)=O.C1([I+]C2=CC=CC=C2)=CC=CC=C1 |
InChi Key | SBQIJPBUMNWUKN-UHFFFAOYSA-M |
Shipping | AMBIENT |
Short Term Storage | RT |
Long Term Storage | RT |
Handling Advice | Protect from light and moisture. |
Use / Stability | Stable for at least 2 years after receipt when stored at RT. |
Hazard statements | H315-H319-H335 |
Precautionary statements | P261-P305 + P351 + P338 |
GHS Symbol | GHS07 |
Signal word | Warning |
Transportation | Not dangerous goods |
References | (1) J.L. Dektar & N.P., J. Org. Chem. 55, 639 (1990), (2) J.H. Ryan & P.J. Stang, Tetrahed. Lett. 38, 5061 (1997), (3) S.A. Jacobsen, et al., J. Chem. Soc. Perkin Trans. I 1999, 3265 (1999), (4) U. Radhakrishnan & P.J. Stang, Org. Lett. 3, 859 (2001), (5) V.K. Aggarwal & B. Olofsson, Angew. Chem. Int. Ed. 44, 5516 (2005), (6) J.-M. Becht & C. Drian, Org. Lett. 10, 3161 (2008), (7) J. Aydin, et al., Org. Lett. 11, 2852 (2009), (8) D. Kumar & V.B. Reddy, Synthesis 10, 1687 (2010), (9) D. Lapointe, et al., Org. Chem. 76, 749 (2011), (10) J.-M. Becht, Encycl. Reag. Org. Synth. (2011) |
Quantity | 5 g, Bulk |