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    (-)-Camphoric acid

    Available from stock

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      (-)-Camphoric acid

      SKU
      C0144

      Category: Building Blocks, Intermediates, Reagents

      Synonyms
      (1S,3R)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid
      560-09-8
      CAS-Number
      C10H16O4
      Molecular Formula
      200.23
      Molecular Weight

      • Product Data
      • Handling
      • Safety Information
      • Details

      Specifications

      Purity
      ≥99% (T)
      Identity
      1H-NMR
      Appearance
      White crystalline powder

      Properties

      Optical Activity
      [α]20/D -48±2°, c = 10% in ethanol
      Melting Point
      184-189 °C
      Solvents
      ethanol, methanol, water
      Shipping
      AMBIENT
      Use / Stability
      Stable for at least 2 years after receipt when stored at -20°C.
      Handling Advice
      Protect from light and moisture.
      Long Term Storage
      -20°C
      Short Term Storage
      +4°C
      Transportation
      Not dangerous goods
      Description
      Chirality inducing agent. Useful tool as resolving agent to separate the isomers and purify racemic mixtures (e.g. DL-lysine) by fractionally crystallizing the product to obtain the pure isomer (e.g. D-lysine). Can also be used as building block.
      InChi
      InChI=1S/C10H16O4/c1-9(2)6(7(11)12)4-5-10(9,3)8(13)14/h6H,4-5H2,1-3H3,(H,11,12)(H,13,14)
      References
      (1) C.P. Berg , J. Biol. Chem. 115, 15 (1936) , (2) K.K. Bisht & E. Suresh , JACS 135, 15690 (2013) , (3) K.K. Bisht, et al.: Acta Crystallogr. B Struct. Sci. Cryst. Eng. Mater. 70, 63 (2014)
      InChi Key
      LSPHULWDVZXLIL-UHFFFAOYSA-N
      Smiles
      C[C@@]1(C(O)=O)C(C)(C)[C@H](C(O)=O)CC1

      Chirality inducing agent. Useful tool as resolving agent to separate the isomers and purify racemic mixtures (e.g. DL-lysine) by fractionally crystallizing the product to obtain the pure isomer (e.g. D-lysine). Can also be used as building block.

      SKU: C0144 Category: Building Blocks, Intermediates, Reagents
      • Additional information

      Additional information

      Synonyms

      (1S,3R)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid

      Purity

      ≥99% (T)

      Appearance

      White crystalline powder

      CAS-Number

      560-09-8

      Molecular Formula

      C10H16O4

      Molecular Weight

      200.23

      Identity

      1H-NMR

      Solvents

      ethanol, methanol, water

      Melting Point

      184-189 °C

      Optical Activity

      [α]20/D -48±2°, c = 10% in ethanol

      Smiles

      C[C@@]1(C(O)=O)C(C)(C)[C@H](C(O)=O)CC1

      InChi Key

      LSPHULWDVZXLIL-UHFFFAOYSA-N

      Shipping

      AMBIENT

      Short Term Storage

      +4°C

      Long Term Storage

      -20°C

      Handling Advice

      Protect from light and moisture.

      Use / Stability

      Stable for at least 2 years after receipt when stored at -20°C.

      Transportation

      Not dangerous goods

      References

      (1) C.P. Berg, J. Biol. Chem. 115, 15 (1936), (2) K.K. Bisht & E. Suresh, JACS 135, 15690 (2013), (3) K.K. Bisht, et al.: Acta Crystallogr. B Struct. Sci. Cryst. Eng. Mater. 70, 63 (2014)

      InChi

      InChI=1S/C10H16O4/c1-9(2)6(7(11)12)4-5-10(9,3)8(13)14/h6H,4-5H2,1-3H3,(H,11,12)(H,13,14)

      Quantity

      1 g, 10 g, Bulk

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