Specifications
- Purity
- ≥95% (NMR)
- Appearance
- Red to dark purple powder
- Identity
- 1H-NMR
Properties
- Solvents
- DMSO
- Fluorescence
- λex 458 nm, λem 612 nm in 0.1 M Tris pH 7.0
Category: Fluorescent Detection
Ru(bpy)2(phen-5-NH2)(PF6)2 is a fluorescent metal-ligand complex probe. It shows high brightness and large Stokes Shift. Spectral Data: λex=458nm, λem=612nm in 0.1 M Tris pH 7.0. It has been used as starting material for synthesis of long-lifetime luminescent Ru complexes and in the preparation of amino-ruthenium(ii) complex functionalized gold nanoparticles, which could be used as probe in biosensors and bioassays. Ru(bpy)2(phen-5-NH2)(PF6)2 is has also been used to synthesize fluorescent silica nanoparticles with ultrabrightness and photostability by encapsulating it into silica nanoparticles by a modified reversed microemulsion method. Could be used for the determination of nucleotide base sequences.
Synonyms | Ru(bpy)2(phen-5-NH2)(PF6)2, Bis-(2,2′-bipyridin)-(5-amino-phenanthrolin)ruthenium bis(hexafluorophosphat) |
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Purity | ≥95% (NMR) |
Appearance | Red to dark purple powder |
CAS-Number | 84537-86-0 |
Molecular Formula | C32H25N7Ru · 2 PF6 |
Molecular Weight | 898.59 |
Identity | 1H-NMR |
Solvents | DMSO |
Fluorescence | λex 458 nm, λem 612 nm in 0.1 M Tris pH 7.0 |
Smiles | "C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC2=CC(=C3C=CC=NC3=C2N=C1)N.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.[Ru+2] |
InChi Key | QQMMCXKCYXQNNA-UHFFFAOYSA-N |
Shipping | AMBIENT |
Short Term Storage | -20°C |
Long Term Storage | -20°C |
Handling Advice | Protect from light and moisture. |
Use / Stability | Stable for at least 2 years after receipt when stored at -20°C. |
Transportation | Not dangerous goods |
References | (1) C.D. Ellis, et at., Inorg. Chem. 22, 1283 (1983), (2) E. Terpetschnig, et al., Anal. Biochem. 251, 241 (1997), (3) F.N. Castellano et al., Anal. Bioch. 255, 165 (1998), (4) J.H. Snook, et al., Org. Electron. 6, 55 (2005), (5) J. Weh, et al., ChemBioChem 8, 122 (2007), (6) Y. Yu, et al., J. Mat. Chem. 21, 12622 (2011), (7) E. de la Llave, et al., J. Phys. Chem. C 118, 21420 (2014), (8) D. Lu, et al., RSC Adv. 6, 51597 (2016), (9) T. Wang, et al., Anal. Chim. Acta 1062, 124 (2019), (10) D. Bahari, et al., Anal. Chim. Acta 1132, 55 (2020) |
InChi | InChi=1S/C12H9N3.2C10H8N2.2F6P.Ru/c13-10-7-8-3-1-5-14-11(8)12-9(10)4-2-6-15-12,2*1-3-7-11-9(5-1)10-6-2-4-8-12-10,2*1-7(2,3,4,5)6,/h1-7H,13H2,2*1-8H,,,/q,,,2*-1,+2 |
Quantity | 5 mg, Bulk |
cdx-Emission max. | 612 ± 5 nm |