Available from stock

4-Bromomethyl-7-methoxycoumarin

SKU: B0022

Categories: Fluorescent Detection, Fluorescent Detection

Synonyms: BMC , Br-Mmc , 4-(Bromomethyl)-7-methoxy-2H-1-benzopyran-2-one; 35231-44-8
CAS-Number: C₁₁H₉BrO₃
Molecular Formula: 269.09
Molecular Weight

For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.

Product Data
Handling
Safety Information
Details

Specifications

Purity: ≥97% (HPLC)
Appearance: Off-white to beige powder
Identity: 1H-NMR

Properties

Solvents: chloroform (20 mg/ml), DMSO, acetone, methanol (sparingly), and water (slightly)
Melting Point: 213-215°C
Boiling Point: 385.3° C at 760 mmHg
Fluorescence: λex 312 nm, λem 395 nm in methanol

Documentation

Safety Data Sheet (SDS): CDX B0022 MSDS.pdf

Shipping: AMBIENT
Short Term Storage: RT
Long Term Storage: +4°C
Handling Advice: Protect from light and moisture.
Use / Stability: Stable for at least 2 years after receipt when stored at +4°C.

Hazard statements: H302-H315-H319-H335
Precautionary statements: P261-P305 + P351 + P338
GHS Symbol: GHS07
Signal word: Warning
RIDADR: UN3335 9
Transportation: Packing Group III

Description: Blue fluorescent labeling reagent for fatty acids and carboxylates. Used for fluorometric analysis, derivatization, and TLC and HPLC separation of a range of naturally occurring acids. Used as a substrate for measuring histone acetyltransferase (HATs), peptidases and sirtuin activity.
Smiles: O=C1OC2=CC(OC)=CC=C2C(CBr)=C1
InChi Key: CTENSLORRMFPDH-UHFFFAOYSA-N
References: W. Duenges, Anal. Chem. 49, 442 (1977) , S. Lam & E. Grushka, J. Chromatogr. A 158, 207 (1978) , S. Yoshida, et al., J Chromatogr. 383, 61 (1986) , J.H. Wolf & J. Korf, J. Pharm. Biomed. Anal. 10, 99 (1992) (Review) , K. Wang, et al., J. Am. Soc. Mass. Spectr. 9, 970 (1998) , C. G. Knight, Lett. Pept. Sci. 5, 1 (1998) , J. Peris Vicente, et al., J. Chromatogr. A. 1076, 44 (2005) , Z. Xie, et al., J. Chromatogr. Sci. 45, 405 (2007) , Z. Chen & Y.G. Zheng, Heterocycl. Commun. 13, 343 (2007) , H. Abromeit, et al., Electrophoresis 33, 1652 (2012)
InChi: InChI=1S/C11H9BrO3/c1-14-8-2-3-9-7(6-12)4-11(13)15-10(9)5-8/h2-5H,6H2,1H3

Blue fluorescent labeling reagent for fatty acids and carboxylates. Used for fluorometric analysis, derivatization, and TLC and HPLC separation of a range of naturally occurring acids. Used as a substrate for measuring histone acetyltransferase (HATs), peptidases and sirtuin activity.

SKU: B0022 Categories: Fluorescent Detection, Fluorescent Detection

Additional information

Additional information

Synonyms	BMC, Br-Mmc, 4-(Bromomethyl)-7-methoxy-2H-1-benzopyran-2-one
Purity	≥97% (HPLC)
Appearance	Off-white to beige powder
CAS-Number	35231-44-8
Molecular Formula	C11H9BrO3
Molecular Weight	269.09
Identity	1H-NMR
Solvents	chloroform (20 mg/ml), DMSO, acetone, methanol (sparingly), and water (slightly)
Melting Point	213-215°C
Boiling Point	385.3° C at 760 mmHg
Fluorescence	λex 312 nm, λem 395 nm in methanol
Smiles	O=C1OC2=CC(OC)=CC=C2C(CBr)=C1
InChi Key	CTENSLORRMFPDH-UHFFFAOYSA-N
Shipping	AMBIENT
Short Term Storage	RT
Long Term Storage	+4°C
Handling Advice	Protect from light and moisture.
Use / Stability	Stable for at least 2 years after receipt when stored at +4°C.
Hazard statements	H302-H315-H319-H335
Precautionary statements	P261-P305 + P351 + P338
GHS Symbol	GHS07
Signal word	Warning
RIDADR	UN3335 9
Transportation	Packing Group III
References	W. Duenges, Anal. Chem. 49, 442 (1977), S. Lam & E. Grushka, J. Chromatogr. A 158, 207 (1978), S. Yoshida, et al., J Chromatogr. 383, 61 (1986), J.H. Wolf & J. Korf, J. Pharm. Biomed. Anal. 10, 99 (1992) (Review), K. Wang, et al., J. Am. Soc. Mass. Spectr. 9, 970 (1998), C. G. Knight, Lett. Pept. Sci. 5, 1 (1998), J. Peris Vicente, et al., J. Chromatogr. A. 1076, 44 (2005), Z. Xie, et al., J. Chromatogr. Sci. 45, 405 (2007), Z. Chen & Y.G. Zheng, Heterocycl. Commun. 13, 343 (2007), H. Abromeit, et al., Electrophoresis 33, 1652 (2012)
InChi	InChI=1S/C11H9BrO3/c1-14-8-2-3-9-7(6-12)4-11(13)15-10(9)5-8/h2-5H,6H2,1H3
Quantity	1 g, 5 g, Bulk