Bis(4-methylphenyl)iodonium hexafluorophosphate

Category: Building Blocks, Intermediates, Reagents

Handling Advice: Protect from light and moisture.
Use / Stability: Stable for at least 2 years after receipt when stored at +4°C.
Long Term Storage: +4°C
Short Term Storage: +4°C
Shipping: AMBIENT

Description: Building block for synthesis. Reagent used for electrophilic phenylation, e.g. of malonates and dithiocarboxylates.
InChi: InChI=1S/C14H14I.F6P/c1-11-3-7-13(8-4-11)15-14-9-5-12(2)6-10-14
InChi Key: LHLVGWWCRPPKBC-UHFFFAOYSA-N
Smiles: F[P-](F)(F)(F)(F)F.CC1=CC=C([I+]C2=CC=C(C)C=C2)C=C1

Building block for synthesis. Reagent used for electrophilic phenylation, e.g. of malonates and dithiocarboxylates.

Additional information

Synonyms	Bis(p-tolyl)iodonium hexafluorophosphate
Purity	≥98% (NMR)
Appearance	White crystalline powder
CAS-Number	60565-88-0
Molecular Formula	C14H14F6IP
Molecular Weight	454.13
Identity	1H-NMR
Solvents	chloroform
Melting Point	175 – 180 °C
Smiles	F[P-](F)(F)(F)(F)F.CC1=CC=C([I+]C2=CC=C(C)C=C2)C=C1
InChi Key	LHLVGWWCRPPKBC-UHFFFAOYSA-N
Shipping	AMBIENT
Short Term Storage	+4°C
Long Term Storage	+4°C
Handling Advice	Protect from light and moisture.
Use / Stability	Stable for at least 2 years after receipt when stored at +4°C.
Hazard statements	H314
Precautionary statements	P280, P305 + P351 + P338, P310
GHS Symbol	GHS05
Signal word	Danger
RIDADR	UN1759 8
Transportation	Excepted Quantities
InChi	InChI=1S/C14H14I.F6P/c1-11-3-7-13(8-4-11)15-14-9-5-12(2)6-10-14
Quantity	10 g, 125 g, Bulk